Interfacial assembly of sandwich mixed (phthalocyaninato)(porphyrinato) rare earth triple-decker complexes [(Pc)Eu(Pc)Eu(TPyP)] (1) and [(TPyP)Sm(Pc)Sm(TPyP)] (2) (Pc = phthalocyaninate, TPyP = meso-tetrakis(4-pyridyl)porphyrinate) has been comparatively studied at the air/pure water and the air/ Cd
Controllable Self-assembly of Sandwich-type Mixed (phthalocyaninato)(porphyrinato) Rare Earth Triple-Decker Complexes
✍ Scribed by Jian Gao; Dapan Li; Yanli Chen
- Publisher
- Springer
- Year
- 2011
- Tongue
- English
- Weight
- 286 KB
- Volume
- 21
- Category
- Article
- ISSN
- 1053-0495
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## Abstract Raman spectroscopic data in the range 500–1800 cm^−1^ for a series of 15 mixed [tetrakis(4‐chlorophenyl)porphyrinato](phthalocyaninato) double‐decker complexes with tervalent rare earths M^III^(TClPP)(Pc) (M = Y, LaLu except Ce and Pm) and intermediate‐valent cerium Ce(TClPP)(Pc) were
## Abstract Mixed phthalocyaninato tetrakis(4‐pyridyl)porphyrinato rare earth triple‐decker complexes M~2~(TPyP)~2~(Pc) [M = La (1), Eu (2)] have been prepared by condensation between M(TPyP)acac generated in situ and M(Pc)~2~. Their symmetrical structure (TPyP)M(Pc)M(TPyP) was verified by ^1^H NMR
## Abstract The half‐sandwich rare‐earth complexes [M^III^(acac)(TClPP)] (M=Sm, Eu, Y; TClPP=__meso__‐tetrakis(4‐chlorophenyl)porphyrinate; acac=acetylacetonate), generated in situ from [M(acac)~3~]⋅__n__ H~2~O and H~2~(TClPP), were treated with 1,8,15,22‐tetrakis(3‐pentyloxy)phthalocyanine [H~2~{P