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Vibrational spectroscopy of phthalocyanine and naphthalocyanine in sandwich-type (na)phthalocyaninato and porphyrinato rare earth complexes

✍ Scribed by Jianzhuang Jiang; Meng Bao; Llew Rintoul; Dennis P. Arnold

Publisher
Elsevier Science
Year
2006
Tongue
English
Weight
812 KB
Volume
250
Category
Article
ISSN
0010-8545

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## Abstract The half‐sandwich rare‐earth complexes [M^III^(acac)(TClPP)] (M=Sm, Eu, Y; TClPP=__meso__‐tetrakis(4‐chlorophenyl)porphyrinate; acac=acetylacetonate), generated in situ from [M(acac)~3~]⋅__n__ H~2~O and H~2~(TClPP), were treated with 1,8,15,22‐tetrakis(3‐pentyloxy)phthalocyanine [H~2~{P