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Control of the Regio- and Stereoselectivity in Diels–Alder Reactions with Quinone Boronic Acids

✍ Scribed by María C. Redondo; Marcos Veguillas; María Ribagorda; M. Carmen Carreño

Publisher: John Wiley and Sons
Year: 2009
Tongue: English
Weight: 403 KB
Volume: 121
Category: Article
ISSN: 0044-8249
DOI: 10.1002/ange.200803428

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✦ Synopsis

Font on the occasion of his 70th birthday Scheme 2. Diels-Alder reactions of 3 a-c with cyclopentadiene and the X-ray structure of 4 b. Scheme 3. Diels-Alder reactions of 3 a-c with 1-subtituted-1,3-butadienes and the X-ray structure of trans-fused 5 a.

Scheme 4. Reaction of dimethylquinonyl boronic acids 3 a-c with isoprene and the X-ray structure of dimmer 8.

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