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Control of regiospecificity in ionic Diels-Alder reactions. The use of allylic alcohols and allylic ethers as precursors of dienophilic allyl cations

✍ Scribed by Gassman, Paul G.; Singleton, Daniel A.


Book ID
126333228
Publisher
American Chemical Society
Year
1986
Tongue
English
Weight
300 KB
Volume
51
Category
Article
ISSN
0022-3263

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A study of t he p i-fa c ial sel e ctivit y o f the Diels -Alder reaction of N -ben~oyl 5methox ycarbonyl-2-a~a-oxabi cyclo[2 .2.2]oct-4-ene, a rigid electron de f i cie nt dienoph i l e bearing t wo allylic axial heteroat om subst ituents, with I -me thoxy-3-trimet h ylsil yl oxybut adi ene , a r e