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Diels-Alder cycloadditions of rigid dienophiles: A probe for allylic axial substituent control of the pi-facial selectivity in the Diels-Alder reaction

✍ Scribed by Dale L. Boger; Mona Patel

Publisher
Elsevier Science
Year
1986
Tongue
French
Weight
200 KB
Volume
27
Category
Article
ISSN
0040-4039

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✦ Synopsis

A study of t he p i-fa c ial sel e ctivit y o f the Diels -Alder reaction of N -ben~oyl 5methox ycarbonyl-2-a~a-oxabi cyclo[2 .2.2]oct-4-ene, a rigid electron de f i cie nt dienoph i l e bearing t wo allylic axial heteroat om subst ituents, with I -me thoxy-3-trimet h ylsil yl oxybut adi ene , a r epresentative ele ctron ri ch diene, i s d etail ed.

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