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Control of regioselectivity in the palladium catalyzed telomerization of isoprene with diethylamine; synthesis of a new head-to-head terpene amine

✍ Scribed by Wilhelm Keim; Michael Röper; Marianne Schieren


Book ID
103691922
Publisher
Elsevier Science
Year
1983
Weight
934 KB
Volume
20
Category
Article
ISSN
0304-5102

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## Abstract Palladium‐catalyzed amination of 7‐bromo‐4‐methyl‐2,1,3‐benzothiadiazole (**7**) with benzophenone imine as an ammonia equivalent is described as a new, safe and practical alternative to nitration for the synthesis of 7‐amino‐4‐methyl‐2,1,3‐benzothiadiazole (**1**) in high yield. This m