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Palladium-Catalyzed Amination with Benzophenone Imine as a New, Safe and Practical Alternative to Nitration for the Synthesis of 7-Amino-2,1,3-benzothiadiazoles.

✍ Scribed by Yugang Liu; Mahavir Prashad; Oljan Repic; Thomas J. Blacklock

Publisher
John Wiley and Sons
Year
2004
Weight
105 KB
Volume
35
Category
Article
ISSN
0931-7597

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✦ Synopsis

Abstract

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Palladium-catalyzed amination with benzo
Palladium-catalyzed amination with benzophenone imine as a new, safe and practical alternative to nitration for the synthesis of 7-amino-2,1,3-benzothiadiazoles
✍ Yugang Liu; Mahavir Prashad; Oljan Repič; Thomas J. Blacklock 📂 Article 📅 2003 🏛 Journal of Heterocyclic Chemistry 🌐 English ⚖ 31 KB 👁 1 views

## Abstract Palladium‐catalyzed amination of 7‐bromo‐4‐methyl‐2,1,3‐benzothiadiazole (**7**) with benzophenone imine as an ammonia equivalent is described as a new, safe and practical alternative to nitration for the synthesis of 7‐amino‐4‐methyl‐2,1,3‐benzothiadiazole (**1**) in high yield. This m