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Control of Product Selectivity by a Styrene Additive in Ruthenium-Catalyzed C−H Arylation

✍ Scribed by Hiroshima, Shun; Matsumura, Daiki; Kochi, Takuya; Kakiuchi, Fumitoshi


Book ID
127155542
Publisher
American Chemical Society
Year
2010
Tongue
English
Weight
575 KB
Volume
12
Category
Article
ISSN
1523-7060

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ChemInform Abstract: Control of Product
✍ Shun Hiroshima; Daiki Matsumura; Takuya Kochi; Fumitoshi Kakiuchi 📂 Article 📅 2011 🏛 John Wiley and Sons ⚖ 29 KB 👁 2 views

Control of Product Selectivity by a Styrene Additive in Ruthenium-Catalyzed C-H Arylation. -The selectivity in the mono-and disubstitution of acetophenones with aryl boronates (I) is investigated. Without an additive, the process gives mainly diarylation products as the major products, whereas the u