## Abstract Difunctional epoxy siloxane monomers containing disiloxane, trisiloxane, and tetrasiloxane were prepared by hydrosilylation of an α,ω‐difunctional SiH‐terminated siloxane with a vinyl‐functional epoxide. Cationic polymerization of these monomers using 3‐methyl‐2‐butenyltetramethylenesu
Control of cationic epoxy polymerization by supramolecular initiation
✍ Scribed by Vidil, Thomas; Tournilhac, François; Leibler, Ludwik
- Book ID
- 118231127
- Publisher
- The Royal Society of Chemistry
- Year
- 2013
- Tongue
- English
- Weight
- 451 KB
- Volume
- 4
- Category
- Article
- ISSN
- 1759-9954
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## Abstract The cationic polymerization of isobutylene with weak Lewis acids, such as BBr~3~ and FeBr~3~, has been studied. These halides are unable to induce individually the polymerization in nonpolar solvents, such as heptane or toluene, or they only initiate the polymerization to low conversion
A series of epoxy alcohols were prepared by simple, straightforward methods. These compounds were very reactive monomers that polymerized rapidly on UV irradiation in the presence of cationic photoinitiators. The kinetics of the cationic photopolymerization of these monomers were studied with diaryl