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Contribution to the bromination of conjugate unsaturated ketones: Synthesis of α,β-unsaturated bromo ketones

✍ Scribed by V. Calo'; L. Lopez; G. Pesce; P.E. Todesco

No coin nor oath required. For personal study only.

✦ Synopsis

Selective bromination of a&unsaturated ketones has been achieved by the action of 2,4,4,6tetrabromocyclohexa-2$dienone.

The stereochemistry, conformation and relative stability of the bromination products of some steroidic unsaturated ketones have been also determined.

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