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Contribution of Polymer-Solvent Interactions to Dynamics of Linear Polymers in Dilute Solutions

✍ Scribed by Ryszard Szorek

Publisher
John Wiley and Sons
Year
2001
Tongue
English
Weight
157 KB
Volume
10
Category
Article
ISSN
1022-1344

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✦ Synopsis

Log(G99 -xg s ) plotted as a function of log(xf pb 02 P/6 kT).

πŸ“œ SIMILAR VOLUMES

An approach to direct renormalization of
An approach to direct renormalization of polymer properties in dilute solution
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## Abstract The properties of long polymer chains in solution can be determined by direct renormalization of the mean‐square end‐to‐end polymer distance and the effective interaction between two chains. The equations for these quantities, correct up to first order in Ξ΅ = __4__ βˆ’ __d__, are derived.

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Critical temperatures for polystyrene/methyl acetate (PS/MA) and polystyrene/ethyl formate (PS/EF) solutions were measured at positive (PS/MA, PS/EF) and negative (PS/MA) pressure. The results confirm that solvent quality is sensitive to pressure; some solvents, designated Q, at P nominal Γ‡ 0, under