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Contribution A L'Étude de L'Action des Bases sur les Sels D'Ammonium Quaternaires. III – Dégradation de l'iodure de 4-méthyl-4-benzylmorpholinium

✍ Scribed by L. P. A. Fery; L. van Hove


Publisher
Wiley (John Wiley & Sons)
Year
2010
Weight
732 KB
Volume
69
Category
Article
ISSN
0037-9646

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Contribution A L'étude De L'Action Des B
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## Abstract In order to examine the importance of Sommelet and Stevens rearrangement versus β‐elimination, the reaction of sodium amide in liquid ammonia on 1‐methyl‐benzylpiperidinium iodide was examined and found to give three isomeric tertiary bases: two of them resulting from a Sommelet rearran

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The reaction of sodium amide in liquid ammonia on l-methyl-l-benzylpyrrolidinium iodide was examined and found to give two isomeric tertiary bases: one of them (yield 86%) results from a Sommelet rearrangement, the other (yield 5%) is formed through a Stevens rearrangement. Dans un article priceden

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Reaction of 2-methyl-2-benzyl-l,2,3,4-tetrahydroisoquinolinium iodide with sodium amide in liquid ammonia yields 76% l-orthotolyl-2-methy1-1,2,3,4-tetrahydroisoquinoline resulting from a Sommelet-Hauser rearrangement. In the same conditions, 2,2-dimethyl-1,2,3,4-tetrahydroisoquinolinium iodide yield