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Contrasting Binding Modes in Lanthanoid Pyrazolate and Pseudo-pyrazolates Prepared by Oxidation of Lanthanoid(II) Complexes and Lanthanoid Metals with Thallium(I) Reagents

โœ Scribed by Deacon, Glen B.; Delbridge, Ewan E.; Fallon, Gary D.; Jones, Cameron; Hibbs, David E.; Hursthouse, Michael B.; Skelton, Brian W.; White, Allan H.


Book ID
126993913
Publisher
American Chemical Society
Year
2000
Tongue
English
Weight
146 KB
Volume
19
Category
Article
ISSN
0276-7333

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Ytterbium metal reacts with thallium(I) 3,5-diphenylpyrazo-razolate complex, [Yb(Ph 2 pz) 2 (DME) 2 ]. The molecular struclate, or with diphenylmercury and 3,5-diphenylpyrazole ture reveals eight coordinate ytterbium(II) with two cisoid ฮท 2 -(Ph 2 pzH) in tetrahydrofuran or 1,2-dimethoxyethane (DME)