It is shown that the excitation profiles of the various Stokes vibrational transitions show the same nodal structure as the initial wavefunctions of the continuum resonance Raman scattering process and hence indicate a reflection principle derived earlier theoretically by others. Continuum resonance
Continuum resonance Raman scattering in 127I35Cl. Evidence of two excited electronic states
โ Scribed by M. Ganz; J. Strempel; W. Kiefer
- Publisher
- Elsevier Science
- Year
- 1993
- Tongue
- English
- Weight
- 619 KB
- Volume
- 207
- Category
- Article
- ISSN
- 0009-2614
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โฆ Synopsis
Polarized and depolarized continuum resonance Raman spectra of isotopically pure 1*713SC1 vapor have been recorded with excitation from the green to the blue spectral region. The spectra have been simulated, applying time-dependent and time-independent second-order perturbation theory. This together with the interpretation of depolarization ratios has been used to get information on the excited state potential functions and their specific contributions to the resonance Raman scattering intensity.
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Ti:c: complex rcsommcc Raman spcctia of molecular bromine have been .malyrcd quantitatively and a clear dcmonrtration of interfcrencc in the Ranun intensity from the L@IIQ+~) nnd 1 111, excited s:stes has been found.