The solution copolymerization of ethylene (1) with octene-1 (2) in Isopar E using constrained geometry catalyst system, [C 5 Me 4 (SiMe 2 N t Bu)]TiMe 2 (CGC-Ti)/ tris(pentafluorophenyl)boron (TPFPB)/modified methylaluminoxane (MMAO), has been carried out in a high-temperature, high-pressure continu
Continuous solution copolymerization of ethylene with propylene using a constrained geometry catalyst system
β Scribed by Shinjoon Park; Wen-Jun Wang; Shiping Zhu
- Publisher
- John Wiley and Sons
- Year
- 2000
- Tongue
- English
- Weight
- 82 KB
- Volume
- 201
- Category
- Article
- ISSN
- 1022-1352
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
Copolymerization of ethylene with a symmetrical diene, namely, 2,5-norbornadiene was studied using a homogeneous metallocene/MAO catalyst system. Copolymerizations were found to occur exclusively through one of the two equally reactive endocyclic double bonds with Cp 2 ZrCl 2 , (buCp) 2 ZrCl 2 and E
## Abstract A highβactivity ZieglerβNatta catalyst of TiCl~4~βsupported MgCl~2~ (ethoxide type) was prepared. Ethyl benzoate (EB) and polydimethylsiloxane (PDMS) were used as internal donors, while __p__βmethyl toluate (MPT) and triethylaluminum (TEA) were used as the external donor and cocatalyst,