## Abstract An analysis of the bulk polymerization of styrene by azobisisobutyronitrile in a tubular reactor was made. Rigorous models were developed and verified. A diffusion model gave predictions of molecular weights and conversions that were 2% higher on the average than the experimental values
Continuous production of polystyrene in a tubular reactor: Part I
β Scribed by J. P. A. Wallis; R. A. Ritter; H. Andre
- Publisher
- American Institute of Chemical Engineers
- Year
- 1975
- Tongue
- English
- Weight
- 701 KB
- Volume
- 21
- Category
- Article
- ISSN
- 0001-1541
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β¦ Synopsis
Abstract
An experimental analysis of the bulk polymerization of styrene initiated by azobisisobutyronitrile was carried out in a tubular reactor.
The experiments performed in a 2.362βcm I.D., 6βmeter long jacketed reactor showed that: (1) it was feasible for a tubular reactor to produce acceptable quality polystyrene for industrial purposes; (2) the quality of the polymer product was reproducible at any time; (3) it was technically feasible for the tubular reactor to replace the stirredβbatch kettles as the preliminary stage in the polystyrene manufacturing process, and (4) radial temperature gradients were not a problem for reactor operation.
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