Abs/raet--Dilatometry was used to measure the rates of copolymerizations of styrene with hex-l-ene, hept-1 -ene, 4-methylpent-1 -erie and 4-methylbex-1 -erie, in the catalyst system, AIEtr-uTiC13 in toluene. The copolymerizatinns were found to be first order with respect to TiCI3 and independent of
β¦ LIBER β¦
Continuous olefin copolymerization with soluble Ziegler-Natta catalysts
β Scribed by Kee Jeong Kim; Kyu Yong Choi
- Publisher
- American Institute of Chemical Engineers
- Year
- 1991
- Tongue
- English
- Weight
- 506 KB
- Volume
- 37
- Category
- Article
- ISSN
- 0001-1541
No coin nor oath required. For personal study only.
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AbstractmThe concept of localized concentrations of monomer adsorbed on a catalytic surface is applied to a kinetic scheme for copolymerization by Ziegler-Natta catalysts. The equations derived are compared with those of Valvassori's approach and with other experimental results.