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Copolymerization with Ziegler-Natta catalysts—II. Monomer reactivity ratios for several olefin pairs

✍ Scribed by I.H. Anderson; G.M. Burnett; W.C. Geddes


Publisher
Elsevier Science
Year
1967
Tongue
English
Weight
484 KB
Volume
3
Category
Article
ISSN
0014-3057

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Copolymerization with Ziegler-Natta cata
✍ I.H. Anderson; G.M. Burnett; W.C. Geddes 📂 Article 📅 1967 🏛 Elsevier Science 🌐 English ⚖ 488 KB

Abs/raet--Dilatometry was used to measure the rates of copolymerizations of styrene with hex-l-ene, hept-1 -ene, 4-methylpent-1 -erie and 4-methylbex-1 -erie, in the catalyst system, AIEtr-uTiC13 in toluene. The copolymerizatinns were found to be first order with respect to TiCI3 and independent of