The scope of the tungstic acid catalyzed hydroyen pe roxi de epoxidation of olefinic alcohols is exauined , at room temperature, i n buffered pr ot i c media. Epoxidation occurs with compl ete retention of configuration for bot h cis and tr ans al kenes . Chemoselectivity is dis cussed with respect
โฆ LIBER โฆ
Continuous hydrogen peroxide production by organic buffers in phytoplankton culture media
โ Scribed by Jeffrey Morris, J.; Zinser, Erik R.; Post, A.
- Book ID
- 121686017
- Publisher
- John Wiley and Sons
- Year
- 2013
- Tongue
- English
- Weight
- 227 KB
- Volume
- 49
- Category
- Article
- ISSN
- 0022-3646
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The aqueous tungstic acid-catalyzed hydrogen peroxide epoxidation of allyl i c al coho1s affo rds the same major di astereo i somer as the VO( acac) 2/tBu OOH system with quite connarab le stereoselectiviti es . In cont r ast , epoxidatIon of honeallylic al cohol s appears t o be much less stereos e