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Epoxidations with 30% hydrogen peroxide catalyzed by tungstic acid in buffered media

✍ Scribed by Denis Prat; Robert Lett

Publisher
Elsevier Science
Year
1986
Tongue
French
Weight
226 KB
Volume
27
Category
Article
ISSN
0040-4039

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✦ Synopsis

The scope of the tungstic acid catalyzed hydroyen pe roxi de epoxidation of olefinic alcohols is exauined , at room temperature, i n buffered pr ot i c media. Epoxidation occurs with compl ete retention of configuration for bot h cis and tr ans al kenes . Chemoselectivity is dis cussed with respect to the olefinic alcohol structure and olefin substi tuents.

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