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Continuous Enantioselective Kinetic Resolution of Terminal Epoxides Using Immobilized Chiral Cobalt—Salen Complexes.

✍ Scribed by Wladimir Solodenko; Gerhard Jas; Ulrich Kunz; Andreas Kirschning

Publisher
John Wiley and Sons
Year
2007
Weight
32 KB
Volume
38
Category
Article
ISSN
0931-7597

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## Abstract Enantiomerically pure epoxides (99%, ee) and diols (98%, ee) from racemic epichlorohydrin, 1,2‐epoxypropane, 1,2‐epoxyhexane, 1,2‐epoxyoctane, and 1,2‐epoxydodecane were obtained in 2–12 h by hydrolytic kinetic resolution (HKR) using the recyclable dimeric homochiral Co(III)–salen compl