Construction of the Cyclopenta[1,3]cyclopropa[1,2-b]naphthalene System in a One-Pot Domino Reaction

A New Performance of the Reaction of PCl

A New Performance of the Reaction of PCl3/AlCl3 with Anisoles − One-Pot and Multi-Step Syntheses of a New Fused-Ring System [1,2,3]Benzoxadiphospholo[2,3-b][1,2,3]benzoxadiphosphole

✍ Graziano Baccolini; Michele Bazzocchi; Carla Boga 📂 Article 📅 2001 🏛 John Wiley and Sons 🌐 English ⚖ 307 KB 👁 2 views

“Biomimetic” Cascade Reactions in Organi

“Biomimetic” Cascade Reactions in Organic Synthesis: Construction of 4-Oxatricyclo[4.3.1.0]decan-2-one Systems and Total Synthesis of 1-O-Methylforbesione via Tandem Claisen Rearrangement/Diels–Alder Reactions

✍ K. C. Nicolaou; Jim Li 📂 Article 📅 2001 🏛 John Wiley and Sons 🌐 English ⚖ 133 KB 👁 2 views

A further demonstration of the value of "biomimetically" inspired synthetic strategies toward natural products is provided by the title reactions that were developed for the construction of 4-oxatricyclo[4.3.1.0]decan-2-one systems from prochiral aromatic precursors. This biomimetic cascade was appl

“Biomimetic” Cascade Reactions in Organi

“Biomimetic” Cascade Reactions in Organic Synthesis: Construction of 4-Oxatricyclo[4.3.1.0]decan-2-one Systems and Total Synthesis of 1-O-Methylforbesione via Tandem Claisen Rearrangement/Diels–Alder Reactions

✍ K. C. Nicolaou; Jim Li 📂 Article 📅 2001 🏛 John Wiley and Sons 🌐 English ⚖ 137 KB 👁 2 views

Palladium(II)-Catalyzed Domino Reaction

Palladium(II)-Catalyzed Domino Reaction of 2-(1-Alkynyl)-2-alken-1-ones with Nucleophiles: Scope, Mechanism and Synthetic Application in the Synthesis of 3,4-Fused Bicyclic Tetrasubstituted Furans

✍ Yuanjing Xiao; Junliang Zhang 📂 Article 📅 2009 🏛 John Wiley and Sons 🌐 English ⚖ 360 KB 👁 2 views

## Abstract magnified image Described herein is the development of a palladium(II)‐catalyzed two‐ or three‐component reaction of 2‐(1‐alkynyl)‐2‐alken‐1‐ones with nucleophiles and allylic chlorides. Various types of nucleophiles such as __O‐__, __N‐__, __C__‐based nucleophiles and olefin‐tethered

The Unexpected Reorganizations of a β-La

The Unexpected Reorganizations of a β-Lactone Aldolate to 1,3-Dioxan-4-ones in the Reaction of 4-(1-Methylethyl)-3-[(phenylthio)methyl]-1-oxetan-2-one Lithium Enolate with Acetaldehyde

✍ Víctor Oswaldo Nava-Salgado; Waldemar Adam 📂 Article 📅 2000 🏛 John Wiley and Sons 🌐 English ⚖ 299 KB

One-Pot Suzuki/Heck Sequence for the Syn

One-Pot Suzuki/Heck Sequence for the Synthesis of (E)-Stilbenes Featuring a Recyclable Silica-Supported Palladium Catalyst via a Multi-Component Reaction in 1,3-Propanediol

✍ Lionel Joucla; Giuseppe Cusati; Catherine Pinel; Laurent Djakovitch 📂 Article 📅 2010 🏛 John Wiley and Sons 🌐 English ⚖ 493 KB 👁 1 views