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“Biomimetic” Cascade Reactions in Organic Synthesis: Construction of 4-Oxatricyclo[4.3.1.0]decan-2-one Systems and Total Synthesis of 1-O-Methylforbesione via Tandem Claisen Rearrangement/Diels–Alder Reactions

✍ Scribed by K. C. Nicolaou; Jim Li


Publisher
John Wiley and Sons
Year
2001
Tongue
English
Weight
137 KB
Volume
113
Category
Article
ISSN
0044-8249

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“Biomimetic” Cascade Reactions in Organi
✍ K. C. Nicolaou; Jim Li 📂 Article 📅 2001 🏛 John Wiley and Sons 🌐 English ⚖ 133 KB 👁 2 views

A further demonstration of the value of "biomimetically" inspired synthetic strategies toward natural products is provided by the title reactions that were developed for the construction of 4-oxatricyclo[4.3.1.0]decan-2-one systems from prochiral aromatic precursors. This biomimetic cascade was appl