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Construction of an Alternating (Rh, Rh, Ir, Ir)∞-Columnar Structure via a Quasiracemate

✍ Scribed by Prof. Dr. Volker Schurig; Wolfgang Pille; Prof. Dr. Werner Winter

Publisher
John Wiley and Sons
Year
1983
Tongue
English
Weight
236 KB
Volume
22
Category
Article
ISSN
0044-8249

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✍ Rolf-Dieter Hoffmann; Rainer Pöttgen 📂 Article 📅 2000 🏛 John Wiley and Sons 🌐 German ⚖ 174 KB 👁 1 views

CaRhIn, CaRhIn 2 , and CaIrIn 2 were synthesized by reacting the elements in glassy carbon crucibles under an argon atmosphere in a high-frequency furnace. CaRhIn adopts the TiNiSi structure: Pnma, a = 730.0(4) pm, b = 433.1(2) pm, c = 828.8(4) pm, wR2 = 0.0707, 630 F 2 values, 20 variables. The CaR