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ChemInform Abstract: CaRhIn with TiNiSi Type Structure and CaMIn2 (M: Rh, Ir) with a New Filled Version of the Zintl Phase CaIn2.

✍ Scribed by Rolf-Dieter Hoffmann; Rainer Poettgen


Publisher
John Wiley and Sons
Year
2010
Weight
34 KB
Volume
31
Category
Article
ISSN
0931-7597

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CaRhIn with TiNiSi Type Structure and Ca
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CaRhIn, CaRhIn 2 , and CaIrIn 2 were synthesized by reacting the elements in glassy carbon crucibles under an argon atmosphere in a high-frequency furnace. CaRhIn adopts the TiNiSi structure: Pnma, a = 730.0(4) pm, b = 433.1(2) pm, c = 828.8(4) pm, wR2 = 0.0707, 630 F 2 values, 20 variables. The CaR

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