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ChemInform Abstract: SrRhIn2, SrPdIn2, SrIrIn2, and SrPtIn2 — New Intermetallic Compounds with a Filled Variant of the CaIn2 Structure.

✍ Scribed by Rolf-Dieter Hoffmann; Ute Ch. Rodewald; Rainer Poettgen


Publisher
John Wiley and Sons
Year
2010
Weight
28 KB
Volume
30
Category
Article
ISSN
0931-7597

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Abstract

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CaRhIn with TiNiSi Type Structure and Ca
✍ Rolf-Dieter Hoffmann; Rainer Pöttgen 📂 Article 📅 2000 🏛 John Wiley and Sons 🌐 German ⚖ 174 KB

CaRhIn, CaRhIn 2 , and CaIrIn 2 were synthesized by reacting the elements in glassy carbon crucibles under an argon atmosphere in a high-frequency furnace. CaRhIn adopts the TiNiSi structure: Pnma, a = 730.0(4) pm, b = 433.1(2) pm, c = 828.8(4) pm, wR2 = 0.0707, 630 F 2 values, 20 variables. The CaR