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Constructing and testing the thermodynamic limits of synthetic NAD(P)H:H2 pathways

✍ Scribed by Andrea Veit; M. Kalim Akhtar; Taeko Mizutani; Patrik R. Jones

Book ID
114899554
Publisher
Wiley (Blackwell Publishing)
Year
2008
Tongue
English
Weight
260 KB
Volume
1
Category
Article
ISSN
1751-7907

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Hydride transfer mechanisms of the reductions of xanthylium ion by NAD(P)H analogues (i.e. BNAH, HEH and AcrH 2 ) were investigated. Both the kinetic observations and an analysis of thermodynamic driving forces for each mechanistic step in all the possible mechanisms indicate that the reductions are