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Constraint and electronegativity effects on selenium-77-phosphorus-31 spin-spin couplings in selenophosphoryl compounds

✍ Scribed by Kroshefsky, R. D.; Weiss, R.; Verkade, J. G.


Book ID
127366077
Publisher
American Chemical Society
Year
1979
Tongue
English
Weight
556 KB
Volume
18
Category
Article
ISSN
0020-1669

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Long-range nuclear spin–spin coupling be
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## Abstract The coupling constants ^n^__J__(^77^Se^31^P), __n__ = 1–4, have been measured in the proton‐decoupled ^31^P NMR spectra of a range of diphosphorus selenides and diselenides. ^31^P–{^1^H, ^31^P} and ^31^P–{^1^H, ^77^Se} triple resonance experiments have been used to establish the signs o