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Nuclear magnetic resonance of phosphorus compounds. VII. Evidence for steric effects on the phosphorus-31-selenium-77 coupling and phosphorus-31 chemical shifts

โœ Scribed by Pinnell, Robert P.; Megerle, Clifford A.; Manatt, Stanley L.; Kroon, Paulus A.


Book ID
120879839
Publisher
American Chemical Society
Year
1973
Tongue
English
Weight
232 KB
Volume
95
Category
Article
ISSN
0002-7863

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Comparison of steric effects on 31P chem
โœ Lory B. Littlefield; Louis D. Quin ๐Ÿ“‚ Article ๐Ÿ“… 1979 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 356 KB

Phosphorus-31 NMR spectra were obtained+ on both syn and anti isomers of norbornenes with the 7-position bearing CI,P-, Me,P-, Me,(S)P-and Me,P as substituents. Norbornanes with 7-C12P-and 7-MezP-were also studied. Just as is true for 13C shits for 7-Me in these bicydo[2.2.l]heptane derivatives, the