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Conservation of helicity and helical character matching in chiral interactions

✍ Scribed by David Zhigang Wang

Publisher
John Wiley and Sons
Year
2005
Tongue
English
Weight
431 KB
Volume
17
Category
Article
ISSN
0899-0042

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✦ Synopsis

An electronic theory for molecular chirality and chiral interactions has recently been published that suggests that underlying chiral interactions is the conservation of molecular electronic helicity and that enantioselectivity in a reaction can be maximized when the interacting chiral components are helically matched. Herein are presented proofs for these principles, and their connections with other theories and implications for the design of chiral catalysts are discussed.

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