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Self-Assembly in Helical Columnar Mesophases and Luminescence of Chiral 1H-Pyrazoles

✍ Scribed by Eduardo Beltrán; Emma Cavero; Joaquín Barberá; José Luis Serrano; Anabel Elduque; Raquel Giménez


Publisher
John Wiley and Sons
Year
2009
Tongue
English
Weight
330 KB
Volume
15
Category
Article
ISSN
0947-6539

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## Abstract Compounds [{Au(pz)(PPh~3~)}~2~] (pz=3,5‐disubstituted pyrazolato; R=BuOC~6~H~4~ (bp), 1; R=C~8~H~17~OC~6~H~4~ (op), 2; R=C~6~H~13~OC~6~H~4~ (hp), 3) were easily obtained by reaction of [Au(NO~3~)(PPh~3~)] and the corresponding pyrazolato ligand. They exhibit similar NMR patterns, their