Self-Assembly in Helical Columnar Mesophases and Luminescence of Chiral 1H-Pyrazoles
✍ Scribed by Eduardo Beltrán; Emma Cavero; Joaquín Barberá; José Luis Serrano; Anabel Elduque; Raquel Giménez
- Publisher
- John Wiley and Sons
- Year
- 2009
- Tongue
- English
- Weight
- 330 KB
- Volume
- 15
- Category
- Article
- ISSN
- 0947-6539
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📜 SIMILAR VOLUMES
The standard RP-HPLC mode with a conventional octadecylsilicapacked column and the chiral chelate (-)(M)(,⌳)-[4,4Ј-((1S)-methyl-(2R)propylethanediyldiimino)bis(pent-3-en-2-onato)]nickel(II), with a flexible, helically selfassembled structure, as the chiral selector in a mobile phase of acetonitrile-
## Abstract Compounds [{Au(pz)(PPh~3~)}~2~] (pz=3,5‐disubstituted pyrazolato; R=BuOC~6~H~4~ (bp), 1; R=C~8~H~17~OC~6~H~4~ (op), 2; R=C~6~H~13~OC~6~H~4~ (hp), 3) were easily obtained by reaction of [Au(NO~3~)(PPh~3~)] and the corresponding pyrazolato ligand. They exhibit similar NMR patterns, their