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Consecutive carbon-carbon bond formation via the π-allylpalladium variant of the Heck reaction

✍ Scribed by Christine S. Nylund; John M. Klopp; Steven M. Weinreb

Book ID: 104214553
Publisher: Elsevier Science
Year: 1994
Tongue: French
Weight: 339 KB
Volume: 35
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)73335-1

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✦ Synopsis

Two C-C bonds SE readily fcamed by nucleophilic addition of stabilized carbanions to the xallylpalladium intermediate regioselectively produced by the Heck reaction of a vinyl bmmide and an unactivated olefin. An intramolecular version of this condensation gives functional&d carhobicyclic compounds as products.

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