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Carbon-carbon bond formation via the reaction of trialkylallylstannanes with organic halides

✍ Scribed by Keck, Gary E.; Yates, John B.


Book ID
127203303
Publisher
American Chemical Society
Year
1982
Tongue
English
Weight
398 KB
Volume
104
Category
Article
ISSN
0002-7863

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Consecutive carbon-carbon bond formation
✍ Christine S. Nylund; John M. Klopp; Steven M. Weinreb πŸ“‚ Article πŸ“… 1994 πŸ› Elsevier Science 🌐 French βš– 339 KB

Two C-C bonds SE readily fcamed by nucleophilic addition of stabilized carbanions to the xallylpalladium intermediate regioselectively produced by the Heck reaction of a vinyl bmmide and an unactivated olefin. An intramolecular version of this condensation gives functional&d carhobicyclic compounds