✦ LIBER ✦

Conjugated molecules in strong magnetic fields

✍ Scribed by L. N. Labzowsky; Yu. E. Lozovik

Publisher: John Wiley and Sons
Year: 1973
Tongue: English
Weight: 270 KB
Volume: 7
Category: Article
ISSN: 0020-7608
DOI: 10.1002/qua.560070513

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✦ Synopsis

Abstract

The spin rearrangement of π‐electrons in the ground state of a conjugated molecule in a strong magnetic field H is discussed. The spin S of the molecule increases as the field H increases (intramolecular paramagnetism). The dependence S(H) for linear and cyclic conjugated molecules in the free‐electron model and in the Hückel‐London approximation is derived. For the cyclic molecules the diamagnetic effects are taken into account.

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