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Conjugate Addition of Lithium N -Phenyl- N -(α-methylbenzyl)amide: Application to the Asymmetric Synthesis of ( R )-(−)-Angustureine

✍ Scribed by Bentley, Scott A.; Davies, Stephen G.; Lee, James A.; Roberts, Paul M.; Thomson, James E.

Book ID
126041814
Publisher
American Chemical Society
Year
2011
Tongue
English
Weight
883 KB
Volume
13
Category
Article
ISSN
1523-7060

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ChemInform Abstract: Conjugate Addition
ChemInform Abstract: Conjugate Addition of Lithium N-Phenyl-N-(α-methylbenzyl)amide: Application to the Asymmetric Synthesis of (R)-(-)-Angustureine.
✍ Scott A. Bentley; Stephen G. Davies; James A. Lee; Paul M. Roberts; James E. Tho 📂 Article 📅 2011 🏛 John Wiley and Sons ⚖ 32 KB 👁 1 views

## Abstract It is found that addition of lithium N‐phenyl‐N‐(α‐methylbenzyl)amide to various α,β‐unsaturated methoxyphenyl esters provides β‐amino esters with excellent diastereoselectivity.