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ChemInform Abstract: Conjugate Addition of Lithium N-Phenyl-N-(α-methylbenzyl)amide: Application to the Asymmetric Synthesis of (R)-(-)-Angustureine.

✍ Scribed by Scott A. Bentley; Stephen G. Davies; James A. Lee; Paul M. Roberts; James E. Thomson

Publisher: John Wiley and Sons
Year: 2011
Weight: 32 KB
Volume: 42
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.201135061

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✦ Synopsis

Abstract

It is found that addition of lithium N‐phenyl‐N‐(α‐methylbenzyl)amide to various α,β‐unsaturated methoxyphenyl esters provides β‐amino esters with excellent diastereoselectivity.

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