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Conformations of side chains of somatostatin very high field proton NMR studies

✍ Scribed by David H. Live; Donald G. Davis; William C. Agosta; David Cowburn

Publisher
John Wiley and Sons
Year
1982
Tongue
English
Weight
425 KB
Volume
19
Category
Article
ISSN
0749-1581

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✦ Synopsis

Abstract

The high field proton NMR spectra (500 and 600 MHz) of the peptide hormone somatostatin in D~2~O are reported. The results obtained are used to derive values of the couplings and chemical shifts related to the solution conformation of several of the side chains. This work resolves a discrepancy in the literature concerning the assignments of resonances in the spectrum. It also provides a means of testing the accuracy of obtaining values for these couplings and shifts in previous 2D NMR studies at lower field from strongly coupled multiplets in spectra of this complexity.

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