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Conformations of Bicyclopropyl and Bicyclobutyl by Electron Diffraction

✍ Scribed by Prof. Dr. O. Bastiansen; Dipl.-Chem. A. de Meijere


Publisher
John Wiley and Sons
Year
1966
Tongue
English
Weight
230 KB
Volume
5
Category
Article
ISSN
0044-8249

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Conformational Analysis of Bicyclopropyl
✍ Prof. Dr. W. LΓΌttke; Dipl.-Chem. A. de Meijere; Prof. Dr. H. Wolff; Dr. H. Ludwi πŸ“‚ Article πŸ“… 1966 πŸ› John Wiley and Sons 🌐 English βš– 197 KB πŸ‘ 2 views

On reaction with N,N-dichloro-t-butylamine or -cyclohexylamine in benzene at 0 "C, nickel tetracarbonyl evolves three moles of carbon monoxide per mole. A colorless precipitate ( I ) is formed that has a Ni:N ratio of 1 : 1 and is insoluble in the usual solvents. 2 RNClz + 2 Ni(CO)4 + 2 [RNClzNi(CO)