Conformations and electronic properties of alkyl peroxides, alkylperoxy radicals and alkoxy radicals
β Scribed by K. Ohkubo; T. Fujita; H. Sato
- Publisher
- Elsevier Science
- Year
- 1977
- Tongue
- English
- Weight
- 673 KB
- Volume
- 36
- Category
- Article
- ISSN
- 0022-2860
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π SIMILAR VOLUMES
A photoinitiation technique has been used to study the gas-phase reactions of specific alkylperoxy radicals derived from azomethane and 2,3-dimethylbutane. The rate of production of radicals is controlled and measured at temperatures (~100Β°C), where the number of reactions is reduced so as to permit
## Abstract The recombination reactions of prototypical alkyl radicals (R) with O~2~, R + O~2~ β RO~2~, have been investigated theoretically by using the variational transition state theory and RiceβRamspergerβKasselβMarcus theory/master equation calculations based on the CASPT2(7,5)/augβccβpVDZ//B