Whereas simple 4,4Ј-bi(1,3-dioxanyl)s 16 and 19 displayed little conformational preference at the inter-ring bond, their derivatives 4 and 13, with equatorial methyl groups in the 5and 5Ј-positions, each showed a strong conformational preference to populate a conformation with a gauche arrangement o
✦ LIBER ✦
Conformational transformations of 4-methyl-1,3-dioxan-2-one
✍ Scribed by A. E. Kuramshina; S. A. Bochkor; V. V. Kuznetsov
- Book ID
- 111465007
- Publisher
- SP MAIK Nauka/Interperiodica
- Year
- 2009
- Tongue
- English
- Weight
- 171 KB
- Volume
- 45
- Category
- Article
- ISSN
- 1070-4280
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## Abstract __N__‐Benzyloxy‐3‐hydroxycarbonsäureamide **7** reagieren mit Phosgen unter geeigneten Bedingungen zu 3‐Benzyloxy‐5,6‐dihydro‐2__H__‐1,3‐oxazin‐2,4(3__H__)‐dionen **8** und 4‐Benzyloxyimino‐1,3‐dioxan‐2‐onen **6**. Die katalytische Hydrierung von **6** ergibt 4‐Hydroxyimino‐1,3‐dioxan‐2