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Conformational study of phosphothreonine in aqueous solution. H and 13C NMR results

✍ Scribed by L. Pogliani; D. Ziessow

Publisher
John Wiley and Sons
Year
1978
Tongue
English
Weight
250 KB
Volume
11
Category
Article
ISSN
0749-1581

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✦ Synopsis

Abstract

The 270 MHz ^1^H and 22.6 MHz ^13^C NMR spectra of DL‐phosphothreonine in D~2~O have been measured and analysed as a function of pD. The trans‐trans conformation of the fragment H‐αC‐αC‐βOP predominates at all pD values. The C‐β—O gauche contribution is notably larger for pD values in the range 7≤pD<10 than for acidic or more basic solutions which is in accordance with earlier results for phosphoserine (PSer).

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