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Conformational studies of β-glucans

✍ Scribed by B. K. Sathyanarayana; V. S. R. Rao

Publisher
Wiley (John Wiley & Sons)
Year
1972
Tongue
English
Weight
34 KB
Volume
11
Category
Article
ISSN
0006-3525

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Conformational Studies of β-glucans
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## Synopsis A study of the effect of linkage on the possible conformations of di-and polysaccharides of a-D-glucose and also the probable intramolecular hydrogen bonds has been made. The differences in the nature of linkage is shown to effect the energetically preferred conformations; (1 -. , 2) l

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A chiroptical method of conformational analysis is applied to linear ( 1 + 3 ) -p-D-glucans and the dimeric analogues pand a-laminaribioside. The method is based on a recently developed semiempirical calculational model for saccharide optical activity. We conclude that disaccharide conformational en