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Conformational studies of trimethylene sulfite and related compounds IV the conformational energy of the axial SO bond

✍ Scribed by H.F. van Woerden; A.T. de Vries-Miedema


Publisher
Elsevier Science
Year
1971
Tongue
French
Weight
197 KB
Volume
12
Category
Article
ISSN
0040-4039

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Conformational studies of trimethylene s
✍ H.F. van Woerden; H. Cerfontain; C.H. Green; R.J. Reijerkerk 📂 Article 📅 1968 🏛 Elsevier Science 🌐 French ⚖ 237 KB

Conformational studies (1,2) of the cyclic sulfites of 2-substituted-propane-1,3-dials have indicated that these esters occupy preferentially a chair form with axial S=O bond. X-ray analyses (3,4) of two compounds have shown that the sulfite group holds the remainder of the ring in au almost ideal s