๐”– Bobbio Scriptorium
โœฆ   LIBER   โœฆ

Conformational, studies of trimethylene sulfite and related compounds II evidence from the rate of alkaline hydrolysis

โœ Scribed by H.F. van Woerden


Publisher
Elsevier Science
Year
1966
Tongue
French
Weight
188 KB
Volume
7
Category
Article
ISSN
0040-4039

No coin nor oath required. For personal study only.


๐Ÿ“œ SIMILAR VOLUMES


Conformational studies of trimethylene s
โœ H.F. van Woerden; H. Cerfontain; C.H. Green; R.J. Reijerkerk ๐Ÿ“‚ Article ๐Ÿ“… 1968 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 237 KB

Conformational studies (1,2) of the cyclic sulfites of 2-substituted-propane-1,3-dials have indicated that these esters occupy preferentially a chair form with axial S=O bond. X-ray analyses (3,4) of two compounds have shown that the sulfite group holds the remainder of the ring in au almost ideal s

A kinetic study of the alkaline hydrolys
โœ Leo H. Koole; Edith A. T. A. Olders; Marko Opresnik; Henk M. Buck ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 404 KB

## Abstract It can be shown that alkaline hydrolysis of fourโ€coordinated phosphorus (P^IV^) compounds is substantially accelerated if the trigonalโ€bipyramidal (TBP) fiveโ€coordinated phosphorus (P^V^) intermediate in the reaction can exhibit conformational transmission. With the compounds 5aโ€c, it w