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Conformational Studies in the Cyclohexane Series. 2. Phenylcyclohexane and 1-Methyl-1-phenylcyclohexane

✍ Scribed by Wiberg, Kenneth B.; Castejon, Henry; Bailey, William F.; Ochterski, Joseph


Book ID
121297244
Publisher
American Chemical Society
Year
2000
Tongue
English
Weight
89 KB
Volume
65
Category
Article
ISSN
0022-3263

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I3C chemical shift data are reported for a series of para-substituted I-methyl-I-phenylcyclohexanes at 22 and -100 OC. The magnitudes of the SCS at alkyl and cycloalkyl carbon positions are discussed. The SCS at C-methyl and C-4 are significantly different in the two chair conformations. The variati