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Conformational dependence of 13C SCS in 1-methyl-1-phenylcyclohexanes

✍ Scribed by Michael J. Cook; Khalida A. Nasri

Book ID
102529921
Publisher
John Wiley and Sons
Year
1987
Tongue
English
Weight
396 KB
Volume
25
Category
Article
ISSN
0749-1581

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✦ Synopsis

I3C chemical shift data are reported for a series of para-substituted I-methyl-I-phenylcyclohexanes at 22 and -100 OC. The magnitudes of the SCS at alkyl and cycloalkyl carbon positions are discussed. The SCS at C-methyl and C-4 are significantly different in the two chair conformations. The variation at C-methyl is appraised in terms of the orientation of the aromatic ring.

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