Conformational stability of deuterated poly(β-benzyl-l-aspartate) in m-cresol
✍ Scribed by G.E. Gajnos; D.C. Lu; F.E. Karasz
- Book ID
- 119069924
- Publisher
- Elsevier Science
- Year
- 1983
- Tongue
- English
- Weight
- 458 KB
- Volume
- 5
- Category
- Article
- ISSN
- 0141-8130
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## Abstract In order to study the effect of the molecular weight on the crystallinity and conformational changes of poly(β‐benzyl L aspartate) in films, a previous study on high molecular weight samples has been extended to included polymers of low molecular weight, about 3.3 × 10^3^. Films were pr
As the t,emperatiire of solid poly(&benzyl-L-aspart.ate) (PRLA), (CO . N H . C H .-CH2COOCHrCsH,),, in the a-helical form is raised froml.iO"C, the line width and second moment of the proton magnetic resonance (PMR ) sigiial decrease in stages riiitil the conformational transition to the w-helix occ