Conformational rearrangement of 2,6-bis(1-salicyloylhydrazonoethyl)pyridine (H4daps) on complexation. Synthesis and X-ray characterisation of H4daps and its copper helicate complex [Cu(H2daps)(H2O)]2�2CH3CN
✍ Scribed by Bermejo, Manuel R.; Pedrido, Rosa; Gonz�lez-Noya, Ana M.; Romero, Mar�a J.; V�zquez, Miguel; Sorace, Lorenzo
- Book ID
- 120933020
- Publisher
- Royal Society of Chemistry
- Year
- 2003
- Tongue
- English
- Weight
- 690 KB
- Volume
- 27
- Category
- Article
- ISSN
- 1144-0546
- DOI
- 10.1039/B305354G
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📜 SIMILAR VOLUMES
Neutral manganese and nickel complexes of the empirical formulae Mn(H 2 daps)(H 2 O) 0.5 and Ni(H 2 daps) (H 2 O) 1.5 (CH 3 CN) have been prepared by electrochemical syntheses. The structures of the complexes formed from solvents with different donor ability were investigated. Recrystallisation of M
Cu 4 (succinato)(tpmc) 2 ](ClO 4 ) 6 AE 2H 2 O (tpmc = N,N 0 ,N 00 ,N 000 -tetrakis-(2-pyridylmethyl)-1,4,8,11-tetraazacyclotetradecane, succinato = dianion of succinic acid) has been prepared and characterized by elemental analysis, UV/vis, IR, EPR (X-band) spectra, conductivity and magnetization m