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Tetrahydropoxen: 2,2′-(1,2-ethanediylbis(iminomethylene)) bis(pyridine N-oxide) and its complexes. X-ray structure of [Cu(H4-poxen)H2O](ClO4)2·H2O and [Co(poxen)H2O](ClO4)2

✍ Scribed by Roman Boča; Monika Nemeĉková; Martina Vrbová; Peter Baran; Ingrid Svoboda; Hartmut Fuess


Book ID
108427901
Publisher
Elsevier Science
Year
2000
Tongue
English
Weight
172 KB
Volume
19
Category
Article
ISSN
0277-5387

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✍ Mathias S. Wickleder 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 German ⚖ 181 KB 👁 2 views

Single crystals of Lu(ClO 4 ) 3 ´3 H 2 O were obtained by slow dehydration of Lu(ClO 4 ) 3 ´6 H 2 O at 140 °C under flowing argon. The compound crystallizes in the triclinic crystal system (P1, Z = 2, a = 750.3(1), b = 838.4(1), c = 1054.6(2) pm, a = 79.77(2)°, b = 79.18(2), c = 63.83(2), R all = 0.