Conformational Properties of α-Amino Acids Disubstituted at the α-Carbon
✍ Scribed by Alemán, Carlos
- Book ID
- 121426357
- Publisher
- American Chemical Society
- Year
- 1997
- Tongue
- English
- Weight
- 137 KB
- Volume
- 101
- Category
- Article
- ISSN
- 0022-3654
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📜 SIMILAR VOLUMES
The conformational preferences of linear peptides containing a,a-disubstituted a-amino acids, derived from the crystal structures of 28 compounds, are reviewed. In particular, the sensitivity of peptide conformation to the geometry of these unusual amino acids is underlined. We also consider possibl
Copper(salen) complex 1 has been found to catalyse the asymmetric alkylation of enolates derived from a variety of amino acids. There is a clear relationship between the size of the side chain in the substrate and the enantioselectivity of the process, so that the enantioselectivity decreases in the
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